Search results for "Viscous liquid"

showing 10 items of 17 documents

Thermomechanical effects in the flow of a fluid in porous media

2002

This paper deals with analysis, by methods of extended thermodynamics, of the thermomechanical effects which arise in the flow of a weakly viscous fluid in a porous medium. Under the hypothesis that the fluid fills all the interstices among the powder and that the size of the powder grains and of the interstices is much lower than a suitable characteristic length, linearized field equations are written, which include, in a natural way, terms which take into account the Dufour, Soret, and virtual mass effects. As a limiting case when the evolution time of the heat flux goes to infinite and no entropy flux is carried, the flow of liquid helium II in a porous medium is obtained.

Characteristic lengthThermodynamicsViscous liquidComputer Science ApplicationsPhysics::Fluid DynamicsHeat fluxModeling and SimulationMass transferModelling and SimulationHeat transferFluid dynamicsBoundary value problemPorous mediumMathematicsMathematical and Computer Modelling
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A system of conservation laws with discontinuous flux modelling flotation with sedimentation

2019

Abstract The continuous unit operation of flotation is extensively used in mineral processing, wastewater treatment and other applications for selectively separating hydrophobic particles (or droplets) from hydrophilic ones, where both are suspended in a viscous fluid. Within a flotation column, the hydrophobic particles are attached to gas bubbles that are injected and float as aggregates forming a foam or froth at the top that is skimmed. The hydrophilic particles sediment and are discharged at the bottom. The hydrodynamics of a flotation column is described in simplified form by studying three phases, namely the fluid, the aggregates and solid particles, in one space dimension. The relat…

Conservation lawSolid particleApplied MathematicsNumerical analysisSpace dimensionMechanics010501 environmental sciencesViscous liquid01 natural sciencesUnit operation010101 applied mathematicsJump0101 mathematicsMineral processing0105 earth and related environmental sciencesIMA Journal of Applied Mathematics
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Nuclear Spin Relaxation in Viscous Liquids: Relaxation Stretching of Single-Particle Probes

2021

Spin-lattice relaxation rates R1(ω,T), probed via high-field and field-cycling nuclear magnetic resonance (NMR), are used to test the validity of frequency-temperature superposition (FTS) for the reorientation dynamics in viscous liquids. For several liquids, FTS is found to apply so that master curves can be generated. The susceptibility spectra are highly similar to those obtained from depolarized light scattering (DLS) and reveal an excess wing. Where FTS works, two approaches are suggested to access the susceptibility: (i) a plot of deuteron R1(T) vs the spin-spin relaxation rate R2(T) and (ii) a plot of R1(T) vs an independently measured reference time τref(T). Using single-frequency s…

Coupling constantCouplingHot TemperatureMagnetic Resonance SpectroscopyMaterials scienceViscosityTemperatureViscous liquidMagnetic Resonance ImagingMolecular physicsLight scatteringSpectral lineSurfaces Coatings and FilmsSuperposition principleDeuteriumMaterials ChemistryRelaxation (physics)Physical and Theoretical ChemistryThe Journal of Physical Chemistry B
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Theory of heterogeneous viscoelasticity

2015

We review a new theory of viscoelasticity of a glass-forming viscous liquid near and below the glass transition. In our model we assume that each point in the material has a specific viscosity, which varies randomly in space according to a fluctuating activation free energy. We include a Maxwellian elastic term and assume that the corresponding shear modulus fluctuates as well with the same distribution as that of the activation barriers. The model is solved in coherent-potential approximation (CPA), for which a derivation is given. The theory predicts an Arrhenius-type temperature dependence of the viscosity in the vanishing-frequency limit, independent of the distribution of the activatio…

Distribution (number theory)FOS: Physical sciences02 engineering and technologyActivation energyCondensed Matter - Soft Condensed MatterViscous liquidSpace (mathematics)01 natural sciencesmechanical property evaluationViscoelasticityShear modulusViscosity0103 physical sciencesCoherent potential approximation010306 general physicsviscoelasticityglassPhysicsDisordered Systems and Neural Networks (cond-mat.dis-nn)MechanicsCondensed Matter - Disordered Systems and Neural Networks021001 nanoscience & nanotechnologyCondensed Matter Physicsglass relaxationcoherent potential approximation; glass; glass relaxation; mechanical property evaluation; metallic glasses; viscoelasticity; Condensed Matter PhysicsSoft Condensed Matter (cond-mat.soft)metallic glasses0210 nano-technologycoherent potential approximation
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Effects of Rayleigh number length thickness of continent on time of mantle flow reversal

1998

Abstract Numerical experiments are carried out to study the effects of continents on the structure of thermal convection in the mantle. The mantle is modelled by a viscous fluid occupying a horizontally extended rectangular 2-D region of aspect ratio 10:1. Continents are treated as thick rigid heat-conducting plates placed in the mantle, with free-slip and with no-slip conditions. Continents restrict the heat release from the underlying mantle; the mantle material heats up and becomes lighter; as a result, a hot upwelling flow replaces downwelling. We calculate the characteristic time τ of this restructuring for various values of model parameters and obtain analytical approximations for τ a…

GeophysicsMantle wedgeMantle convectionConvective heat transferDownwellingRayleigh numberGeophysicsViscous liquidGeologyMantle (geology)Earth-Surface ProcessesEarth's internal heat budgetJournal of Geodynamics
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Exact mechanical models of fractional hereditary materials

2012

Fractional Viscoelasticity is referred to materials, whose constitutive law involves fractional derivatives of order β R such that 0 β 1. In this paper, two mechanical models with stress-strain relation exactly restituting fractional operators, respectively, in ranges 0 β 1 / 2 and 1 / 2 β 1 are presented. It is shown that, in the former case, the mechanical model is described by an ideal indefinite massless viscous fluid resting on a bed of independent springs (Winkler model), while, in the latter case it is a shear-type indefinite cantilever resting on a bed of independent viscous dashpots. The law of variation of all mechanical characteristics is of power-law type, strictly related to th…

Hereditary materialMechanical EngineeringMathematical analysisConstitutive equationFractional derivativeType (model theory)Viscous liquidCondensed Matter PhysicsPower lawViscoelasticityDashpotFractional calculusClassical mechanicsMechanical fractancePower-lawsMechanics of MaterialsGeneral Materials ScienceIdeal (ring theory)Settore ICAR/08 - Scienza Delle CostruzioniFractional integralMathematicsJournal of Rheology
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Experiments and CFD Predictions of Solid Particle Distribution in a Vessel Agitated with Four Pitched Blade Turbines

2001

The distribution of solid particles in a high aspect-ratio baffled tank agitated with four 45° pitched blade turbines (PBT) was investigated using both experimental measurements and CFD simulations. Dilute suspensions of glass beads in water and moderately viscous liquids were considered. The measurement of axial particle concentration profiles was conducted by means of a light attenuation technique. Fully predictive simulations of solid-liquid suspensions were performed using a Sliding-Grid approach coupled with the Eulerian-Eulerian Two Fluid Model and the ‘homogeneous’ two-phase k-ɛ turbulence model. The simulated particle axial concentration profiles were compared with the experimental …

Materials scienceStirred suspensionPolymers and PlasticsComputer simulationBlade (geometry)business.industryTurbulenceSettore ING-IND/25 - Impianti ChimiciGeneral Chemical EngineeringMixing (process engineering)Pitched blade turbineMechanical engineeringGeneral ChemistryMechanicsComputational Fluid DynamicViscous liquidComputational fluid dynamicsTwo-fluid modelSolids distributionCondensed Matter::Soft Condensed MatterPhysics::Fluid DynamicsMixingMultiple impellerParticlebusinessChemical Engineering Research and Design
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Dynamics of supercooled liquids and glassy solids

2001

Nuclear and High Energy PhysicsMaterials scienceCondensed matter physicsSpin-lattice relaxationDynamics (mechanics)Slow dynamicsSpin–lattice relaxationViscous liquidMultidimensional NMR530BiochemistryAnalytical ChemistryHeterogeneous relaxationOrientational glassesLine-shape analysisStimulated echoesSupercooled liquidsSupercoolingGlass transitionGlass transitionSpectroscopyProgress in Nuclear Magnetic Resonance Spectroscopy
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Zero-field nuclear magnetic resonance spectroscopy of viscous liquids

2014

Abstract We report zero-field NMR measurements of a viscous organic liquid, ethylene glycol. Zero-field spectra were taken showing resolved scalar spin–spin coupling (J-coupling) for ethylene glycol at different temperatures and water contents. Molecular dynamics strongly affects the resonance linewidth, which closely follows viscosity. Quantum chemical calculations have been used to obtain the relative stability and coupling constants of all ethylene glycol conformers. The results show the potential of zero-field NMR as a probe of molecular structure and dynamics in a wide range of environments, including viscous fluids.

Nuclear and High Energy PhysicsZero field NMRzero-field NMRBiophysicsAnalytical chemistryNMR spectroscopy; low field nmr; Density functional calculationsViscous liquidBiochemistrychemistry.chemical_compoundViscosityMolecular dynamicsNMR spectroscopyMoleculePhysics::Chemical Physicsdensity functional theoryCoupling constantlow field nmrtechnology industry and agricultureZero-field NMRNuclear magnetic resonance spectroscopyviscous liquidsCondensed Matter PhysicsScalar couplingDensity functional calculationschemistryChemical physicsDensity functional theoryscalar couplingEthylene glycolViscous liquidsJournal of Magnetic Resonance
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A mechanical picture of fractional-order Darcy equation

2015

Abstract In this paper the authors show that fractional-order force-flux relations are obtained considering the flux of a viscous fluid across an elastic porous media. Indeed the one-dimensional fluid mass transport in an unbounded porous media with power-law variation of geometrical and physical properties yields a fractional-order relation among the ingoing flux and the applied pressure to the control section. As a power-law decay of the physical properties from the control section is considered, then the flux is related to a Caputo fractional derivative of the pressure of order 0 ⩽ β ≤ 1 . If, instead, the physical properties of the media show a power-law increase from the control sectio…

Numerical AnalysisAnomalous diffusionApplied MathematicsVolumetric fluxMass flowAnomalous diffusion; Anomalous scaling; Darcy equation; Fractional derivatives; Porous mediaMathematical analysisPorous mediaAnomalous diffusionFluxFractional derivativeViscous liquidDarcy–Weisbach equationFractional calculusModeling and SimulationDarcy equationSettore ICAR/08 - Scienza Delle CostruzioniPorous mediumAnomalous scalingMathematicsCommunications in Nonlinear Science and Numerical Simulation
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